As a requirement, to be used in a Urea plant the M.S. plate is to be overlaid with stainless steel welding. The base material is SA 516 Gr. 70. The weld over lay is of 6 mm thickness. As per the Snamprogetti specification, the chemical composition on the surface of over lay should be 2 RE69, which is equivalent to 310 MoLN. The essential requirement is that the surface shall be free from deleterious phases like carbides, delta ferrite and sigma phase, whose sensitivity for deterioration in presence of Urea is extremely high.
Several prototype trials were conducted at GMM Pfaulder Ltd Works. All of them were failing in IGC test as per ASTM 262 Practice ‘A’. In view, of the critical nature of requirement, the matter was referred to TCR Advanced Eng. Pvt Ltd. They suggested different welding procedures having varying parameters. The aim was to achieve the faster cooling rates with low heat inputs. IGC and metallography was carried out on all the weld samples. The suitable welding procedure has been recommended that is passing IGC ASTM 262 Practice ‘A’ and showing freedom to sigma phase precipitation which cleared the most stringent corrosion test requirements.
In addition to this, an evaluation was made to find out effectiveness of the SR treatment which is done after the first overlay over carbon steel tube sheet. The approach of micro-hardness profile was adopted. These tests were conducted on sample having single layer and the one acceptable in the IGC practice A as per ASTM 262.
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